Post-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry.

نویسندگان

  • Cyrille Boyer
  • Alexander H Soeriyadi
  • Peter J Roth
  • Michael R Whittaker
  • Thomas P Davis
چکیده

In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exchange chemistry or thiol/ene "click" reactions.

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عنوان ژورنال:
  • Chemical communications

دوره 47 4  شماره 

صفحات  -

تاریخ انتشار 2011